Institutsleitung

Institut für Funktionale Materialien für Nachhaltigkeit
Curriculum Vitae
Prof. Francesca M. Toma is the Director of the Institute of Functional Materials for Sustainability at Helmholtz Zentrum Hereon and a Distinguished Helmholtz Professor at Helmut Schmidt University. Her research centers on the synthesis and characterization of sustainable materials for renewable energy and biological applications. She also holds a position as a Visiting Professor at Lawrence Berkeley National Laboratory.
She earned her Ph.D. in Biophysics from the International School of Advanced Studies in Italy in 2009, and acquired postdoctoral experience at the University of Trieste, before moving to the University of California, Santa Barbara as a Marie Curie Researcher in 2011, and to the University of California, Berkeley in 2013. For nearly a decade, she was as a Staff Scientist at Lawrence Berkeley National Lab, where she served as the Program lead of the Liquid Sunlight Alliance and as the Photoelectrochemistry Technology Lead for HydroGEN. In 2022, she also served for a year as a Detailee in the Catalysis Science Program of the Basic Energy Science of the Department of Energy.
Prof. Toma's has co-authored 120 publications, focusing on (photo)electrocatalysis, drug delivery, and tissue engineering. Her work has garnered international recognition with several awards. She was honored as one of the "100 Women of Materials Science" by the Royal Society of Chemistry in 2018 and received the "Rising Star" Award from the American Chemical Society in 2021. She was also awarded the “Alfredo di Braccio Award” by the Italian Academy of Science. In 2022, she was selected as an Oppenheimer Fellow by the US National Laboratory Directors' Council in 2022, underscoring her contributions as a leader to advancing scientific research. The Division of Energy & Fuels of the American Chemical Society selected her as a finalist for the 2025 Energy Lectureship for the Mid-Career category.
Francesca Tomas Publikationen auf Google Scholar
Francesca Toma @ google scholar
Fancesca Tomas Hereon-Publikationen
- journal articleCopper tantalate by a Sodium-driven flux-mediated synthesis for photoelectrochemical CO2 reductionKöche, Ariadne,Hong, Kootak,Seo, Sehun,Babbe, Finn,Gim, Hyeongyu,Kim, Keon-Han,Choi, Hojoong,Jung, Yoonsung,Oh, Inhyeok,Vaidhyanathan Krishnamurthy, Gnanavel,Störmer, Michael,Lee, Sanghan,Kim, Tae-Hoon,Bell, Alexis T.,Khan, Sherdil,Sutter-Fella, Carolin M.,Toma, Francesca M. (2025)
In: Small Methods, 2401432, WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. - journal articleSurface composition impacts selectivity of ZnTe photocathodes in photoelectrochemical CO2 reduction reactionZeng, G.,Liu, G.,Panzeri, G.,Kim, C.,Song, C.,Alley, O.J.,Bell, A.T.,Weber, A.Z.,Toma, F.M. (2025)
In: ACS Energy Letters, Vol. 10, 34-39, American Chemical Society, Washington DC.
- journal articleA US perspective on closing the carbon cycle to defossilize difficult-to-electrify segments of our economyShaw, W.J.,Kidder, M.K.,Bare, S.R.,Delferro, M.,Morris, J.R.,Toma, F.M.,Senanayake, S.D.,Autrey, T.,Biddinger, E.J.,Boettcher, S.,Bowden, M.E.,Britt, P.F.,Brown, R.C.,Bullock, R.M.,Chen, J.G.,Daniel, C.,Dorhout, P.K.,Efroymson, R.A.,Gaffney, K.J.,Gagliardi, L.,Harper, A.S.,Heldebrant, D.J.,Luca, O.R.,Lyubovsky, M.,Male, J.L.,Miller, D.J.,Prozorov, T.,Rallo, R.,Rana, R.,Rioux, R.M.,Sadow, A.D.,Schaidle, J. A.,Schulte, L.A.,Tarpeh, W.A.,Vlachos, D.G.,Vogt, B.D.,Weber, R.S.,Yang, J.Y.,Arenholz, E.,Helms, B.A.,Huang, W.,Jordahl, J.L.,Karakaya, C.,Kian, K.,Kothandaraman, J.,Lercher, J.,Liu, P.,Malhotra, D.,Mueller, K.T.,O’Brien, C.P.,Palomino, R.M.,Qi, L.,Rodriguez, J.A.,Rousseau, R.,Russell, J.C.,Sarazen, M.L.,Sholl, D.S.,Smith, E.A.,Stevens, M.B.,Surendranath, Y.,Tassone, C.J.,Tran, B.,Tumas, W.,Walton, K.S. (2024)
In: Nature Reviews Chemistry, Vol. 8, 376-400, Springer Nature, Basingstoke. - conference lecture: Boston (USA); 01.12.2024-06.12.2024Ratchet-Based Ion Pumps for Selective Ion SeparationsSegev, G.,Herman, A.,Meltser, D.,Grossman, E.,Shushan-Alshochat, K.,Hirsch, B.,Rosen, B.,Kautz, R.,Ardo, S.,Ager, J.W.,Toma, F.M. (2024)
In: MRS Fall Meeting, Boston (USA), 01.12.2024-06.12.2024. - conference lecture (invited): BTU Cottbus-Senftenberg (DEU); 11.09.2024-13.09.2024CO2 (photo)electroreduction: fundamentals and case examplesToma, Francesca M. (2024)
In: Summer school on "Characterization of micro- and nanomaterials“ 2024, BTU Cottbus-Senftenberg (DEU), 11.09.2024-13.09.2024. - conference lecture (invited): Nürnberg (DEU); 25.09.2024-27.09.2024Closing the carbon cycle: how to make sustainable fuels and productsToma, Francesca M. (2024)
In: Solar Technologies Go Hybrid ‐ SolTech, Nürnberg (DEU), 25.09.2024-27.09.2024.
- journal articleOpportunities for the materials research community to support the development of the H2 economyKu, A.Y.,Kocs, E.A.,Afzal, S.,Ewan, M.,Glenn, J.R.,Toma, F.,Vickers, J.,Weeks, B.,White, A.A. (2023)
In: MRS Energy & Sustainability, Vol. 10, 158-173, Springer, Berlin. - journal articleSuppression of undesired losses in organometal halide perovskite-based photoanodes for efficient photoelectrochemical water splittingChoi, H.,Kim, Y.Y.,Seo, S.,Jung, Y.,Yoo, S.M.,Moon, C.S.,Jeon, N.J.,Lee, S.,Lee, K.,Toma, F.M.,Seo, J. (2023)
In: Advanced Energy Materials, Vol. 13, 31, 2300951, Wiley-VCH, Weinheim. - journal articleBest practices for experiments and reporting in photocatalytic CO2 reductionBonchio, M.,Bonin, J.,Ishitani, O.,Lu, T.B.,Morikawa, T.,Morris, A.J.,Reisner, E.,Sarkar, D.,Toma, F.M.,Robert, M. (2023)
In: Nature Catalysis, Vol. 6, 657-665, Springer Nature, London. - journal articleOrganometal Halide Perovskite-Based Photoelectrochemical Module Systems for Scalable Unassisted Solar Water SplittingChoi, H.,Seo, S.,Yoon, C.J.,Ahn, J.B.,Kim, C.S.,Jung, Y,Kim, Y.,Toma, F.M.,Kim, H.,Lee, S. (2023)
In: Advanced Science, Vol. 10, 33, 2303106, Wiley-VCH, Weinheim. - conference lecture (invited): Boston, MA (USA); 26.11.2023 - 01.12.2023Designing Microenvironments for Selective CO2 (Photo)ElectroreductionToma, F. (2023)
In: MRS Fall Meeting 2023, Boston, MA (USA), 26.11.2023 - 01.12.2023.
Weitere Publikationen (2023-2007)
Weitere Publikationen
- A. M. K. Fehr, T. G. Deutsch, F. M. Toma, M. S. Wong, A. D. Mohite, „Technoeconomic Model and Pathway to< $2/kg Green Hydrogen Using Integrated Halide Perovskite Photoelectrochemical Cells”, ACS Energy Lett. 2023, 8, 4976-4983
- A.M. K. Fehr, A. Agrawal, F. Mandani, C.L. Conrad, Q. Jiang, S. Y. Park, O. Alley, B. Li, S. Sidhik, I. Metcalf, C. Botello, J. L. Young, J. Even, J. C. Blancon, T. G. Deutsch, K. Zhu, S. Albrecht, F. M. Toma, M. Waong, A. D. Mohite, “Integrated halide perovskite photoelectrochemical cells with solar-driven water-splitting efficiency of 20.8%”, Nat. Commun. 2023, 14, 3797
- C. Kim, A. J. King, S. Aloni, F. M. Toma, A. Z. Weber, A. T. Bell, “Codesign of an integrated metal-insulator-semiconductor photocathode for photoelectrochemical reduction of CO2 to ethylene”, Energy Environ. Sci. 2023, 16(7), 2968-2976
- Y. Xiao, X. Kong, S. Vanka, W. J. Dong, G. Zeng, Z. Ye, K. Sun, I. A. Navid, B. Zhou, F. M. Toma, H. Guo, Z. Mi “Oxynitrides enabled photoelectrochemical water splitting with over 3,000 hrs stable operation in practical two-electrode configuration”, Nat. Comm. 2023, 14, 2047
- K. Hong, S. Tan, M. J. McDermott, T. Huang, F. Babbe, T. Kodalle, M. Gallant, S. Seo, F. M. Toma, K. A. Persson, Y. Yang, C. M. Sutter-Fella*, “Shape-Controlled NaTaO3 by Flux-Mediated Synthesis”, Adv. Funct. Mater. 2022, 32, 2206641
- O. J. Alley, K. Wyatt, M. Steiner, G. Liu, T. Kistler, G. Zeng, D. Larson, J. Cooper, J. Young, T. G. Deutsch,* F. M. Toma,* “Best practices in PEC water splitting: How to reliably measure solar-to-hydrogen efficiency of photocathodes”, Front. Energy Res. 2022, 10, 884364
- Z. Zhang, S. A. Lindley,T. Chen, X. Cheng, E. Xie, W. Han, F.M. Toma, J. K. Cooper, “Local Charge Transport at the Interface of Semiconductor and Charge Transport Mediator”, Adv. Optical Mater. 2022, 2201247
- 94. S. Vanka, G. Zeng, T. G. Deutsch, F. M. Toma, Z. Mi, “Long-Term Stability Metrics of Photoelectrochemical Water Splitting”, Front. Energy Res. 2022, 10, 840140
- J. Yano,* K. Gaffney,* J. Gregoire,* L. Hung,* A. Ourmazd,* J. Schrier,* J. Sethian,* and F. M. Toma,* “The Case for Data Science in Experimental Chemistry: Examples and Recommendations”, Nat. Rev. Chem. 2022
- U. Savino, J. Eichhorn, G. Liu, A. Sacco, M. Laurenti, R. Chatterjee, G. Zeng, M. Castellino, K. Bejkta, J. Yano, E. Tresso,*A. Chiodoni,* F. M. Toma,* “Characterization of chemically modified TiO2 synthesized via sustainable super- oxidation of Ti”, J. Phys. Chem C. 2022, 126 (14), 6223–6230
- S. Neppl, J. Mahl, F. Roth, G. Mercurio, G. Zeng, F. M. Toma, N. Huse, P. Feulner, O. Gessner, “Nanoscale Confinement of Photo-Injected Electrons at Hybrid Interfaces”, J. Phys. Chem. Lett. 2021, 12 (49), 11951-11959
- G. Liu, F. Zheng, J. Li, G. Zeng, Y. Ye, D. M. Larson, J. Yano, E. J. Crumlin, J. W. Ager, L.-w. Wang, F. M. Toma,* “Investigation and mitigation of degradation mechanisms in Cu2O photoelectrodes for CO2 reduction to ethylene”, Nat. Energy 2021, 6, 1124-1132
- H. Li, P. Yu, R. Lei, F. Yang, P. Wen, X. Ma, G. Zeng, J. Guo, F. M. Toma, Y. Qiu, S. M. Geyer, X. Wang, T. Cheng, W. S. Drisdell, “Facet-Selective Deposition of Ultrathin Al2O3 on Copper Nanocrystals for Highly Stable CO2 Electroreduction to Ethylene”, Angew. Chem. Int. Ed. 2021, 133 (47), 25042-25047
- A. K. Buckley, T. Cheng, M. H. Oh, G. M. Su, J. Garrison, S. W. Utan, C. Zhu, F. D. Toste*, W. A. Goddard III*, F. M. Toma,* “Approaching 100% Selectivity at Low Potential on Ag for Electrochemical CO2 Reduction to CO Using a Surface Additive” ACS Catal. 2021, 11, 15, 9034–9042
- G. Liu, M. Lee, S. Kwon, G. Zeng, J. Eichhorn, A. K. Buckley, F. D. Toste, W. A. Goddard III,* F. M. Toma,* “CO2 reduction on pure Cu produces only H2 after subsurface O is depleted: theory and experiment”, Proc. Natl. Acad. Sci. U.S.A. 2021, 118(23), e2012649118
- J. Eichhorn, C.-M. Jiang, J. K Cooper, I. D. Sharp, F. M. Toma,* “Nanoscale Heterogeneities and Composition– Reactivity Relationships in Copper Vanadate Photoanodes”, ACS Appl. Mater. Interfaces 2021, 13, 20, 23575–23583
- S. Alia,* D. Ding,* A. McDaniel,* F. M. Toma,* Huyen N. Dinh,* “How to Make Clean Hydrogen AWSM: The Advanced Water Splitting Materials Consortium”, Electrochem. Soc. Interface, Winter Issue 2021, 30, 4, 50-56
- C. Kim, K. M. Cho, K. Park, J. Y. Kim, G.-T. Yun, F. M. Toma, I. Gereige, H.-T. Jung, “Cu/Cu2O Interconnected Porous Aerogel Catalyst for Highly Productive Electrosynthesis of Ethanol from CO2”, Adv. Funct. Mater. 2021, 2102142
- G. Zeng, T. A. Pham, S. Vanka, G. Liu, C. Song, J. K. Cooper, Z. Mi,* T. Ogitsu,* F. M. Toma,* “PhotoelectrochemicallySelf-Improving Si/GaN Photocathode Towards Efficient and Durable H2 Production”, Nat. Mater. 2021, 20, 1130-1135
- 90. L. M. Otto, E. A. Gaulding, C. Chen, T. Kuykendall, A. Hammack, F. M. Toma, D. F. Ogletree, S. Aloni, B. J. H. Stadler, A. M Schwartzberg “Methods for tuning plasmonic and photonic optical resonances in high surface area porous electrodes”, Sci. Rep. 2021, 11, 7656
- T. A. Kistler, G. Zeng, J. L. Young, L.-C. Weng, C. Aldridge, K. Wyatt, M. A. Steiner, O. Solorzano Jr., F. A. Houle, F. M. Toma, A. Z. Weber, T. G. Deutsch, N. Danilovic, “Emergent Degradation Phenomena Demonstrated on Resilient, Flexible and Scalable Integrated Photoelectrochemical Cells”, Adv. Energy Mater. 2020, 2002706
- J. Eichhorn, S. E. Reyes-Lillo, S. Roychoudhury, S. Sallis, J. Weis, D. M. Larson, J. K. Cooper, I. D. Sharp, D. Prendergast, F. M. Toma,* “Revealing Nanoscale Chemical Heterogeneities in Polycrystalline Mo-BiVO4 Thin Films“, Small 2020, 16, 35, 2001600
- M. Borgwardt, J. Mahl, F. Roth, L. Wenthaus, F. Brauße, M. Blum, K. Schwarzburg, G. Liu, F. M. Toma, O. Gessner, “Photoinduced Charge Carrier Dynamics and Electron Injection Efficiencies in Au Nanoparticle-Sensitized TiO2 Determined With Picosecond Time-Resolved X-Ray Photoelectron Spectroscopy”, J. Phys. Chem. Lett. 2020, 11, 14, 5476–5481
- S. H. Lee, I. Sullivan, D. M. Larson, G. Liu, F. M. Toma, C. Xiang, W. S. Drisdell, “Correlating Oxidation State and Surface Area to Activity from Operando Studies of Copper CO Electroreduction Catalysts in a Gas-fed Device”, ACS Catal. 2020, 10, 14, 8000–8011
- F. M. Toma, A. J. Cowan, M. Sugiyama, L. Wang, K. Xi, “Solar to Fuel: Recent developments in conversion of sunlight into high value chemicals” APL Materials 2020
- K. Jiang, Y. Huang, G. Zeng, F. M. Toma, W. A. Goddard, A. T. Bell, “Effects of Surface Roughness on the Electrochemical Reduction of CO2 over Cu”, ACS Energy Lett. 2020, 5 (4), 12061-1204
- K. Jiang, Y. Huang, G. Zeng, F. M. Toma, W. A. Goddard, A. T. Bell, “Effects of Surface Roughness on the Electrochemical Reduction of CO2 over Cu”, ACS Energy Lett. 2020, 5 (4), 12061-1204
- M. Lee, A. De Riccardis, R. V. Kazantsev, J. K. Cooper, A. K. Buckley, P. W. W. Burrough, D. M. Larson, G. Mele, F. M. Toma,* “Aluminum Metal Organic Framework Triggers Carbon Dioxide Reduction Activity”, ACS Appl. Energy Mater. 2020, 3 (2), 1286-1291
- A. De Riccardis, M. Lee, R. V. Kazantsev, A. J. Garza, G. Zeng, D. M. Larson, E. L. Clark, P. Lobaccaro, P. W. W. Burroughs, E. Bloise, J. W. Ager, A. T. Bell, M. Head-Gordon, G. Mele,* F. M. Toma,* “Heterogenized Pyridine- Substituted Cobalt(II) Phthalocyanine Yields Reduction of CO2 by Tuning the Electron Affinity of the Co Center”, ACS Appl. Mater. Interfaces 2020, 12 (5), 5251-5258
- Y. Liu, F. M. Toma, Catalysis: “Qubits from the Bottom Up” Chem 2020, 6(9), pp 795-798
- S. Vanka, K. Sun, G. Zeng, T. A. Pham, F. M. Toma, T. Ogitsu, Z. Mi, “Long-Term Stability Studies of a Semiconductor Photoelectrode Protected by Gallium Nitride Nanostructures”, J. Mater. Chem. A 2019, 7 (48), 27612-27619
- A. K. Buckley, M. Lee, T. Cheng, R. V. Kazantsev, D. M. Larson, W. A. Goddard, F. D. Toste,* F. M. Toma,* “Electrocatalysis at Organic-Metal Interfaces: Identification of Structure-Reactivity Relationships for CO2 Reduction at Modified Cu Surfaces”, J. Am. Chem. Soc. 2019, 141 (18), 7355-7364
- C.-M. Jiang, S. E. Reyes-Lillo, Y. Liang, Y.-S. Liu, G. Liu, F. M. Toma, D. Prendergast, I. D. Sharp, J K. Cooper, “Electronic Structure and Performance Bottlenecks of CuFeO2 Photocathodes”, Chem. Mater. 2019, 31 (7), 2524-2543
- G. Gurudayal, J. W. Beeman, J. Bullock, H. Wang, J. Eichhorn, C. M. Towle, A. Javey, F. M. Toma, N. Mathews, J. W. Ager, “Si photocathode with Ag-supported dendritic Cu catalyst for CO2 reduction”, Energy Environ. Sci. 2019, 12, 1068-1077
- 76. C. T. Chen, J. Pedrini, E. A. Gaulding, C. Kastl, G. Calafiore, S. Dhuey, T. R. Kuykendall, S. Cabrini, F. M. Toma, S. Aloni, A. M. Schwatzberg, “Very high refractive index transition metal dichalcogenide photonic conformal coatings by conversion of ALD metal oxides”, Sci. Rep. 2019, 9, article number: 2768
- C. Kastl, R. J. Koch, C. T. Chen, J. Eichhorn, S. Ulstrup, A. Bostwick, C. Jozwiak, T. R. Kuykendall, N. J. Borys, F. M. Toma, S. Aloni, A. Weber-Bargioni, E. Rotenberg, A. M. Schwartzberg, “Effects of defects on band structure and excitons in WS2 revealed by nanoscale photoemission spectroscopy”, ACS Nano 2019, 13 (2), pp 1284–1291
- L. Li, J. Yang, H. Ali-Loytty, T.-C. Weng, F. M. Toma, D. Sokaras, I. D. Sharp, A. Nilsson, “Operando observation of chemical transformations of iridium oxide during photoelectrochemical water oxidation”, ACS Appl. Energy Mater. 2019, 2 (2), pp 1371–1379
- G. Liu, J. Eichhorn, C.-M. Jiang, M. C. Scott, L. H. Hess, J. M. Gregoire, J. A. Haber, I. D. Sharp, F. M. Toma,* “Interface engineering for light-driven water oxidation: Unravelling the passivating and catalytic mechanism in BiVO4 overlayers”, Sustainable Energy Fuels 2019, 3, 127-135
- J. Eichhorn, C. Kastl, A. M. Schwartzberg, I. D. Sharp, F. M. Toma,* “Disentangling the role of surface chemical interactions on interfacial charge transport at BiVO4 photoanodes”, ACS Appl. Mater. Interfaces 2018, 10 (41), pp 35129-35135
- L. Zhou, A. Shinde, D. Guevarra, F. M. Toma, H. S. Stein, J. M. Gregoire, J. A. Haber, “Balancing surface passivation and catalysis with integrated BiVO4/(Fe-Ce)Ox photoanodes in pH 9 borate electrolyte”, ACS Appl. Energy Mater. 2018, 1 (10), pp 5766-5771
- M. R. Nellist, J. Qiu, F. A. L. Laskowski, F. M. Toma, S. W. Boettcher, “Potential-sensing electrochemical AFM shows CoPi as a hole collector and oxygen evolution catalyst on BiVO4 water-splitting photoanodes”, ACS Energy Lett. 2018, 3 (9), pp 2286-2291
- F. M. Toma,* News and Views: “Disentangling Interfacial Energetics” Nat. Energy 2018, 3, pp 6-7
- J. Eichhorn, C. Kastl, J. K. Cooper, D. Ziegler, A. M. Schwartzberg, I. D. Sharp, F. M. Toma,* “Nanoscale imaging of charge carrier transport limitations in BiVO4 photoanodes”, Nat. Commun. 2018, 9, 2597
- C. M. Sutter-Fella, Q. P. Ngo, N. Cefarin, K. L. Gardner, N. Tamura, C. V. Stan, W. S. Drisdell, A. Javey, F. M. Toma, I. D. Sharp, “Cation-dependent light-induced halide demixing in hybrid organic-inorganic perovskites”, Nanolett. 2018, 18 (6), pp 3473-3480
- J. Eichhorn, G. Liu, F. M. Toma,* “Degradation of Semiconductor Electrodes in Photoelectrochemical Devices: Principles and Case Studies”, in “Integrated Solar Fuel Generators; Energy and Environment Series”, edited by I. D. Sharp, H. A. Lewerenz, H. A. Atwater, Royal Society of Chemistry, ISBN 978-1-78262-555-1
- C.-M. Jiang, G. Segev, L. H. Hess, G. Liu, G. Zaborski, F. M. Toma, J. K. Cooper, I. D. Sharp, “Composition-dependent functionality of copper vanadate photoanodes”, ACS Appl. Mater. Interfaces 2018, 10 (13), pp 10627-10633
- G. Segev, C.-M. Jiang, J. K. Cooper, J. Eichhorn, F. M. Toma, I. D. Sharp, “Quantification of the loss mechanisms in emerging water splitting photoanodes through empirical extraction of the spatial charge collection efficiency”, Energy Environ. Sci. 2018, 11, pp 904-913
- C. M. Sutter-Fella,‡ Y. Li,‡ N. Cefarin, A. K. Buckley, Q. P. Ngo, A. Javey, I. D. Sharp,* F. M. Toma,* “Low pressure vapor-assisted solution process for tunable band gap pinhole-free methylammonium lead halide perovskites films“, J. Vis. Exp. 2017, 127, e55404. ‡These authors contributed equally
- M. Favaro, J. Yang, S. Nappini, E. Magnano, F. M. Toma, E. J. Crumlin, J. Yano, and I. D. Sharp, “Understanding the oxygen evolution reaction mechanism on CoOx using operando ambient pressure X-ray photoelectron spectroscopy”, J. Am. Chem. Soc. 2017, 139 (26), pp 8960-8970
- F. M. Toma,* A. Kudo,* R. Van de Krol,* L. Z. Wang,* “Addressing the Key Aspects of Photoelectrocatalytic Systems for Solar Fuel Production” ACS Energy Lett 2017, 2(12), pp. 2725-2726
- W. S. Drisdell,* L. Leppert, C. M. Sutter-Fella, Y. Liang, Y. Li, Q. P. Ngo, S. Gul, T. Kroll, D. Sokaras, A. Javey, J. Yano, J. B. Neaton, F. M. Toma,* D. Prendergast,* I. D. Sharp,* “Determining atomic-scale structure and composition of organo-lead halide perovskites by combining high-resolution X-ray absorption spectroscopy and first-principles calculations”, ACS Energy Lett. 2017, 2 (5), pp 1183-1189
- E. A. Gaulding, G. Liu, C. T. Chen, L. Löbbert, A. Li, G. Segev, J. Eichhorn, S. Aloni, A. M. Schwartzberg, I. D. Sharp, F. M. Toma,* “Fabrication and optical characterization of polystyrene opal templates for the synthesis of scalable, nanoporous (photo)electrocatalytic materials by electrodeposition”, J. Mater. Chem. A 2017, 5, pp 11601-11614
- C. M. Sutter-Fella, D. W. Miller, Q. P. Ngo, E. T. Roe, F. M. Toma, I. D. Sharp, M. C. Lonergan, A. Javey, “Band tailing and deep defect states in CH3NH3Pb(I1-xBrx)3 perovskites as revealed by sub-bandgap photocurrent”, ACS Energy Lett. 2017, 2 (3), pp 709-715
- M. Favaro, C. Valero-Vidal, J. Eichhorn, F. M. Toma, P. N. Ross, J. Yano, Z. Liu, E. J. Crumlin, “Elucidating the alkaline oxygen evolution reaction mechanism on platinum”, J. Mater. Chem. A 2017, 5, pp 11634-11643
- I. D. Sharp, J. K. Cooper, F. M. Toma, R. Buonsanti, “Bismuth vanadate as a platform for accelerating discovery and development of complex transition metal oxide photoanodes”, ACS Energy Lett. 2017, 2, pp 139-150
- 55. J. Yang, J. K. Cooper, F. M. Toma, M. Favaro, J. W. Beeman, K. Walczak, C. Wang, C. Zhu, S. Gul, J. Yano, C. Kisielowski, A. Schwartzberg, I. D. Sharp, “A multi-functional biphasic water splitting catalyst tailored for integration with high performance semiconductor photoanodes”, Nature Mater. 2017, 16, pp 335-341
- A. Shinde, G. Li, L. Zhou, D. Guevarra, S. K. Kumar, F. M. Toma, J. A. Haber, Q. Yan, J. B. Neaton, J. M. Gregoire, “The role of the CeO 2 /BiVO 4 interface in optimized Fe-Ce coatings for solar fuels photoanodes”, J. Mater. Chem. A 2016, 4, pp 14356-14363
- A. Shinde, D. Guevarra, G. Liu, I. D. Sharp, F. M. Toma,* J. M. Gregoire,* J. A. Haber,* “Discovery of Fe−Ce Oxide/BiVO4 Photoanodes through Combinatorial Exploration of Ni−Fe−Co−Ce Oxide Coatings”, ACS Appl. Mater. Interface. 2016, 8, pp 23696-23705
- Y. Li, J. Cooper, W. Liu, C. Sutter-Fella, M. Amani, A. Javey, J. W. Ager, Y. Liu, F. M. Toma,* I. D. Sharp,* “Defective TiO2 with high photoconductive gain for efficient and stable planar heterojunction perovskite solar cells”, Nat. Commun. 2016, 7, article number: 12446
- J. K. Cooper, S. Scott, Y. Ling, J. Yang, S. Hao, Y. Li, F. M. Toma, M. Stutzmann, K. V. Lakshmi, Sharp I. D. “The role of hydrogen in defining the n-type character of BiVO4 photoanodes”, Chem. Mater. 2016, 28(16), 5761-5771
- F. M. Toma,*,‡ J. K. Cooper, V. Kunzelmann, M. T. McDowell, Jie Yu, D. M. Larson N. J. Borys, C. Abelyan, J. W. Beeman, K. M. Yu, J. Yang, L. Chen, M. R. Shaner, J. Spurgeon, F. A. Houle, K. A. Persson, I. D. Sharp,* “Mechanistic insights into chemical and photochemical transformations of bismuth vanadate photoanodes”, Nat. Commun. 2016, 7, article number: 12012
- S. Y. Leblebici, L. Leppert, Y. Li, S. E. Reyes-Lillo, S. Wickenburg, E. Wong, J. Lee, M. Melli, D. Ziegler, D. K. Angell, D. F. Ogletree, P. D. Ashby, F. M. Toma, J. B. Neaton, I. D. Sharp, A. Weber-Bargioni, “Facet-dependent photovoltaic efficiency variations in single perovskite grains”, Nat. Energy 2016, 1, article number: 16093
- G. D. Nguyen,‡ F. M. Toma,‡ Ting Cao,‡ Z. Pedramrazi, C. Chen, D. J. Rizzo, T. Joshi, C. Bronner, Y.-C. Chen, S. G. Louie, F. R. Fischer, M. F. Crommie, “Bottom-up synthesis of N=13 sulfur-doped graphene nanoribbons”, J. Phys. Chem. C 2016, 120 (5), pp 2684-2687. ‡These authors contributed equally
- C. M. Sutter-Fella,‡ Y. Li,‡ M. Amani, J. W. Ager III, F. M. Toma, E. Yablonovitch, I. D. Sharp, A. Javey, “High photoluminescence quantum yield in band gap tunable bromide containing mixed halide perovskites”, Nanolett. 2016, 16 (1), pp 800-806. ‡These authors contributed equally
- D. Guevarra, A. Shinde, S. K. Suram, I. D. Sharp, F. M. Toma,* J. A. Haber,* J. M. Gregoire,* “Development of solar fuels photoanodes through combinatorial integration of Ni-La-Co-Ce oxide catalysts on BiVO4”, Energy Environ. Sci. 2016, 9, pp 565-580
- M. M. Ristova, C. Francis, F. M. Toma, K. M. Yu, W. Walukiewicz, “Electrochemical modification of the optical and electrical properties of Cd-rich NixCd1-xO alloys”, Sol. Ener. Mat. Sol. C. 2016, 147, 127-133
- D. G. de Oteyza,* J. M. Garcia-Lastra, F. M. Toma,* P. Borghetti, L. Floreano, A. Verdini, A. Cossaro, T. V. Pho, F. Wudl, J. E. Ortega, “Decacyclene-tri-anhydride (DTA) at functional interfaces: an ideal electron acceptor material for organic electronics”, J. Phys. Chem. Lett. 2016, 7, pp 90–95
- C. Guo, W. T. Al-Jamal, F. M. Toma, A. Bianco, M. Prato, K. T. Al-Jamal, K. Kostarelos, “Design of cationic multiwalled carbon nanotubes as efficient siRNA vectors for lung cancer xenograft eradication”, Bioconjugate Chem. 2015, 26 (7), 1370–1379
- L. Chen, J. Yang, S. Klaus, L. Lee, R. Woods-Robinson, J. Ma, J. Cooper, F. M. Toma, L.-W. Wang, I. D. Sharp, A. T. Bell, J. W. Ager, “P-type transparent conducting oxide / n-type semiconductor heterojunctions for efficient and stable solar water oxidation”, J. Am. Chem. Soc. 2015, 137 (30), 9595-9603
- F. M. Toma,‡ F. Puntoriero, T. V. Pho, M. La Rosa, Y.-S. Jun, B. J. Tremolet de Villers, J. Pavlovich, G. D. Stucky, S. Campagna, F. Wudl, “Polyimide dendrimers containing multiple electron donor-acceptor units and their unique photophysical properties”, Angew. Chem. Int. Ed. 2015, 54 (23), 6775-6779
- L. Chen, F. M. Toma, J. K. Cooper, A. Lyon, Y. Lin, I. D. Sharp, J. W. Ager, “Mo-doped BiVO4 photoanodes synthesized by reactive sputtering”, ChemSusChem 2015, 8, 1066-1071
- Jason K. Cooper, Sheraz GuI, F. M. Toma, L. Chen, P.-A. Glans, J. Guo, J. W. Ager, I. D. Sharp, “Indirect bandgap and optical properties of monoclinic bismuth vanadate”, J. Phys. Chem. C 2015, 119(6), 2969-2974
- Y. Li, J. K. Copper, R. Buonsanti, Cinzia Giannini, Y. Liu, F. M. Toma,* I. D. Sharp,* “Fabrication of planar heterojunction perovskite solar cells by controlled low-pressure vapor annealing”, J. Phys. Chem. Lett. 2015, 6(3), 493-499
- S.-L. Cai, Y.-B. Zhang, A. B. Pun, B. He, J. Yang, F. M. Toma, I. D. Sharp, O. M. Yaghi, J. Fan, S.-R. Zheng, W.-G. Zhang, Y. Liu, “Tunable electrical conductivity in oriented thin films of tetrathiafulvalene-based covalent organic framework”, Chem. Sci. 2014, 5, 4693-4700
- J. K. Cooper, S. GuI, F. M. Toma, L. Chen, P.-A. Glans, J. Guo, J. W. Ager, I. D. Sharp, “Electronic structure of monoclinic BiVO4”, Chem. Mater. 2014, 26(18), 5365-5373
- J. Yang, K. Walczak, E. Anzenberg, F. M. Toma, G. Yuan, J. Beeman, A. Schwartzberg, Y. Lin, M. Hettick, A. Javey, J. W. Ager, J. Yano, H. Frei, I. D. Sharp, “Efficient and sustained photoelectrochemical water oxidation by cobalt oxide/silicon photoanodes with nanotextured interfaces”, J. Am. Chem. Soc. 2014, 136(17), 6191-6194
- T. V. Pho, F. M. Toma, B. J. Tremolet de Villers, S. Wang, N. D. Treat, N. Eisenmenger, R. C. Coffin, J. D. Douglas, J. M. J. Fréchet, G. C. Bazan, F. Wudl, M. L. Chabinyc, “Decacyclene triimides: paving the road to universal non-fullerene acceptors for organic photovoltaics”, Adv. Energy. Mater. 2014, 4(5), 1301007
- 33. A. Aldinucci, A. Turco, T. Biagioli, F. M. Toma, D. Bani, D. Guasti, L. Rizzetto, D. Cavalieri, C. Manuelli, L. Massacesi, A. Bianco, L. Ballerini, M. Prato, C. Ballerini, “Carbon nanotube scaffolds instruct human dendritic cells: modulating immune responses by contacts at the nanoscale”, NanoLett. 2013, 12(13), 6098-6105
- A. Fabbro,‡ A. Sucapane,‡ F. M. Toma, E. Calura, L. Rizzetto, C. Carrieri, P. Roncaglia, V. Martinelli, D. Scaini, L. Masten, A. Turco, S. Gustincich, M. Prato, L. Ballerini, “Adhesion to carbon nanotube conductive scaffolds forces action-potential appearance in immature rat spinal neurons”, PLOS One 2013, 9 (8), e73621 1-14. ‡These authors contributed equally
- V. Martinelli,‡ G. Cellot, ‡ F. M. Toma, C. S. Long, J. H. Caldwell, L. Zentilin, M. Giacca, A. Turco, M. Prato, L. Ballerini, and L. Mestroni, “Carbon nanotubes instruct physiological growth and functionally mature syncytia: non-genetic engineering of neonatal cardiac myocytes”, ACS Nano 2013, 7 (7), 5746-5756. ‡These authors contributed equally
- P. Singh, C. Ménard-Moyon, A. Battigelli, F. M. Toma, J. Kumar, N. Nagapradeep, S. Verma, A. Bianco, “Double functionalization of carbon nanotubes with purine and pyrimidine derivatives”, Chem-Asian J. 2013, 8, 1472-1481
- M. Quintana, A. Montellano López, S. Rapino, F. M. Toma, M. Iurlo, M. Carraro, A. Sartorel, C. Maccato, X. Ke, C. Bittencourt, T. Da Ros, G. Van Tendeloo, M. Marcaccio, F. Paolucci, M. Prato, M. Bonchio, “Energy materials by molecular design: knitting the catalytic pattern of artificial photosynthesis to a hybrid graphene nano-texture”, ACS Nano 2013, 7 (1), 811-817
- T. V. Pho, F. M. Toma, M. L. Chabinyc, F. Wudl, “Self-assembling decacyclene triimides prepared via a regioselective hextuple Friedel-Crafts carbamylation”, Angew. Chem. Int. Ed. 2013, 52 (5), 1446-1451
- J. Lee, S. Mubeen, G. Hernandez-Sosa, Y. Sun, F. M. Toma, G. D. Stucky, M. Moskovits, “High Efficiency Panchromatic Hybrid Schottky Solar Cells”, Adv. Mater. 2013, 25 (2), 256–260
- K. T. Al-Jamal, A. Nunes, L. Methven, H. Ali-Boucetta, S. Li, F. M. Toma, M. A. Herrero, W. T. Al-Jamal, H. M. M. ten Eikelder, J. Foster, S. Mather, M. Prato, K. Kostarelos, A. Bianco, “Degree of chemical functionalization of carbon nanotubes determines tissue distribution and excretion profile”, Angew. Chem. Int. Ed. 2012, 51 (26), 6389-6393
- L. Maggini,‡ F. M. Toma,‡ L. Feruglio, J. M. Malicka, T. Da Ros, N. Armaroli, M. Prato, D. Bonifazi, “Luminescent blooming of dendronic carbon nanotubes through ion-pairing interactions with an Eu(III) complex”, Chem-Eur. J. 2012, 18 (19), 5889-5897. ‡These authors contributed equally. Cover page, accepted as VIP article and highlighted by Angewandte Spotlights (Angew. Chem. Int. Ed., 2012, 51, 4514 – 4516
- V. Martinelli,‡ G. Cellot,‡ F. M. Toma, C. Long, J. Caldwell, L. Zentilin, M. Giacca, A. Turco, M. Prato, L. Ballerini, L. Mestroni, “Carbon nanotubes promote growth and spontaneous electrical activity”, NanoLett. 2012, 12 (4), 1831- 1838. ‡These authors contributed equally
- A. Fabbro, A. Villari, J. Laishram, D. Scaini, F. M. Toma, A. Turco, M. Prato, L. Ballerini, “Spinal cord explants use carbon nanotube interfaces to enhance neurite outgrowth and fortify synaptic inputs”, ACSNano 2012, 6 (3), 2041- 2055
- A. Sartorel, M. Carraro, F. M. Toma, M. Prato, M. Bonchio, “Shaping the beating heart of artificial photosynthesis: oxygenic metal oxide nano-clusters”, En. Env. Science 2012, 5 (2), pp 5592-5603. Inside front cover
- A. Fabbro, F. M. Toma, G. Cellot, M. Prato, L. Ballerini “Carbon nanotubes and neuronal performance”, in “Nano medicine and the nervous system”, edited by C. R. Martin, V. R. Preedy, R. J. Hunter, Science Publishers (U.S.), ISBN- 10: 1578087287
- C. Fabbro,‡ F. M. Toma,‡ and T. Da Ros “Biomedical Applications II: Influence of Carbon Nanotubes in Cancer Therapy”, Chapter 3, pp 47-86, in “Carbon Nanotubes: from bench Chemistry to promising Biomedical Applications”, edited by G. Pastorin, Pan Stanford Publishing (*these authors contributed equally to this work), ISBN 978-981-4241- 68-7 (Hardcover)
- P. Singh, G. Lamanna, C. Ménard-Moyon, F. M. Toma, E. Magnano, F. Bondino, M. Prato, S. Verma, A. Bianco, “Formation of efficient catalytic silver nanoparticles on carbon nanotubes by adenine functionalization”, Angew. Chem. Int. Ed. 2011, 59 (42), pp 9893-9897
- G. Cellot, F. M. Toma, Z. Kasap Varley, J. Laishram, A. Villari, M. Quintana, S. Cipollone, M. Prato, L. Ballerini, “Carbon nanotube scaffolds tune synaptic strength in cultured neural circuits: novel frontiers in nanomaterial-tissue interactions”, J. Neurosci. 2011, 31 (36), pp 12945-12953
- F. M. Toma,‡ A. Sartorel, M. Iurlo, M. Carraro, S. Rapino, L. Hoober-Burkhardt, T. Da Ros, M. Marcaccio, G. Scorrano, F. Paolucci, M. Bonchio, M. Prato, “Tailored functionalization of carbon nanotubes for electrocatalytic water splitting and sustainable energy applications”, ChemSusChem 2011, 4 (10), pp 1447-1451
- M. Carraro, A. Sartorel, F. M. Toma, F. Puntoriero, F. Scandola, S. Campagna, M. Prato, M. Bonchio “Artificial photosynthesis challenges: water oxidation at nanostructured interfaces”, Top. Curr. Chem. 2011, 303, pp 121-150
- F. M. Toma,‡ A. Sartorel, M. Carraro, M. Bonchio, M. Prato, “Dendron-functionalized multi walled carbon nanotubes incorporating polyoxometalates for water splitting catalysis”, Pure Appl. Chem. 2011, 83 (8), pp 1529-1542
- P. Singh, F. M. Toma, J. Kumar, V. Venkatesh, M. Prato, J. Raya, S. Verma, A. Bianco, “Carbon nanotubes-nucleobase hybrids: nanorings from uracil-modified single-walled carbon nanotubes”, Chem-Eur. J. 2011, 17 (24), pp 6772-6780
- P. Singh, C. Samorì, F. M. Toma, C. Bussy, A. Nunes, K. T. Al-Jamal, C. Ménard-Moyon, M. Prato, K. Kostarelos, A. Bianco, “Polyamine functionalized carbon nanotubes: synthesis, characterization, cytotoxicity and siRNA binding”, J. Mat. Chem. 2011, 21 (13), pp 4850-4860
- K. Fuchsberger, A. Le Goff, L. Gambazzi, F. M. Toma, A. Goldoni, M. Giugliano, M. Stelzle, M. Prato, “Multi-walled carbon nanotube-functionalized microelectrode arrays fabricated by micro-contact printing: platform for studying chemical and electrical neuronal signaling”, Small 2011, 7 (4), pp 524-530
- A. Sartorel, M. Truccolo, S. Berardi, M. Gardan, M. Carraro, F. M. Toma, G. Scorrano, M. Prato, M. Bonchio, “Oxygenic polyoxometalates: a new class of molecular propellers”, Chem. Comm. 2011, 47 (6), pp 1716-1718. Highlighted by ChemComm Blog, 28 Feb 2011
- F. M. Toma,‡ A. Sartorel, M. Iurlo, M. Carraro, P. Parisse, C. Maccato, S. Rapino, B. Rodriguez Gonzalez, H. Amenitsch,T. Da Ros, L. Casalis, A. Goldoni, M. Marcaccio, G. Scorrano, G. Scoles, F. Paolucci, M. Prato, M. Bonchio, “Efficient water oxidation at carbon nanotube/polyoxometalate electrocatalytic interfaces", Nat. Chem. 2010, 2, 826-831. Highlighted by Nat. Chem., 2010, 2, 804-805
- K. T. Al-Jamal, F. M. Toma, A. Yilmazer, H. Ali-Boucetta, A. Nunes, M. A. Herrero, B. Tian, A. Eddaoui, A. Bianco, M. Prato, K. Kostarelos, “Enhanced cellular internalization and gene silencing with a series of cationic dendron- multiwalled carbon nanotube:siRNA complexes”, FASEB J. 2010, 24 (11), pp 4354-4365
- C. Samorì, R. Sainz, C. Ménard-Moyon, F. M. Toma, E. Venturelli, P. Singh, M. Ballestri, M. Prato, A. Bianco, “Potentiometric titration as a straightforward method to assess the amount of functional groups on shortened carbon nanotubes”, Carbon 2010, 48 (9), pp 2447-2454
- C. Samorì, H. Ali-Boucetta, R. Sainz, C. Guo, F. M. Toma, C. Fabbro, T. Da Ros, M. Prato, K. Kostarelos, A. Bianco, “Enhanced anticancer activity of multi-walled carbon nanotube-methotrexate conjugates using cleavable linkers”, Chem. Commun. 2010, 46 (9), pp 1494-1496
- I. Guryanov, F. M. Toma, A. Montellano López, M. Carraro, T. Da Ros, G. Angelini, E. D’Aurizio, A. Fontana, M. Maggini, M. Prato, M. Bonchio, “Microwave-assisted functionalization of carbon nanostructures in ionic liquids”, Chem-Eur. J. 2009, 15(46), pp 12837-12845
- P. Singh, J. Kumar, F. M. Toma, Raya J., Prato M., Fabre B., Verma S., Bianco A., “Synthesis and characterization of nucleobase-carbon nanotube hybrids”, J. Am. Chem. Soc. 2009, 131 (37), pp 13555-13562
- M. A. Herrero, F. M. Toma, K. T. Al-Jamal, K. Kostarelos, A. Bianco, T. Da Ros, F. Bano, L. Casalis, G. Scoles, M. Prato, “Synthesis and characterization of a carbon nanotube-dendron series for efficient siRNA delivery”, J. Am. Chem. Soc. 2009, 131 (28), pp 9843-9848
- C. Gaillard, G. Cellot, Li Shouping, F. M. Toma, H. Dumortier, G. Spalluto, B. Cacciari and M. Prato, “Carbon nanotubes carrying cell-adhesion peptides do not interfere with neuronal functionality”, Adv. Mater. 2009, 21 (28), pp 2903- 2908
- A. Garcia, M. A. Herrero, S. Frein, R. Deschenaux, R. Munoz, I. Bustero, F. M. Toma, M. Prato, “Synthesis of dendrimer-carbon nanotubes conjugates” Phys. Stat. Sol. (a) 2008, 205 (6), pp 1402-1407
- S. Caffieri, G. Miolo, R. Seraglia, D. Dalzoppo, F. M. Toma, G. M. J. Beijersbergen van Henegouwen, “Photoaddion of fluphenazine to nucleophiles in peptides and proteins. Possible cause of immune side effects”, Chem. Res. Toxicol 2007, 20 (10), pp 1470-1476